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Polyurethanes
are probably the single most versatile material available to the industrial
world. Physical test results do not do justice to the array of real world
properties that polyurethanes provide. Polyurethanes were originally developed
as an alternative material to natural rubber. They have grown far beyond
this combining many attributes of metals, plastics and rubber into one
unique material.
V-THane
polyurethane offers the following service properties:
Hardness
V-THane
polyurethane is supplied in a range of hardnesses from 25° Shore A which
is softer than a pencil rubber or an elastic band to 84° Shore D which
is harder than a golf ball.The table below gives some guidance as to these
hardness ranges.

Compression
When load is applied to a V-THane polyurethane
it deflects but unrestrained surfaces bulge in sympathy. This is because
polyurethane is incompressible and acts like a fluid capable of changing
its shape to the limit of its strength under load. Strictly speaking this
is not compression but nevertheless it is the term used in elastomer technology.
V-THane has a higher load bearing capacity than
that of more conventional elastomers for the same hardness. This characteristic
permits greater design choices and usually allows the use of smaller components.
HPE can offer guidance on polymer selection and
provide indicative load and deflection figures for most compression applications.
Tension
Tensile strength and associated elongation are usually measured as part
of material and process control regimes. It is rare that polyurethane
elastomers are used in tension and then only at a small fractlon of thelr
ultimate strength. Even so V-THane has much higher
tensile strengths than conventional elastomers.
Resilience
While
resilience is generally a function of hardness in conventional elastomers,
this is not true of V-THane polyurethanes. V-THane
can be formulated to give a wide range of resilience values. An added
benefit is that the resilience changes very little between 10°C and 100°C
giving more consistent performance in a variable environment.
Abrasion
When
compared to rubber, plastics and metals V-THane
offers outstanding resistance to wear giving many times the life span
of these conventional materials. V-THane can be
tailored to suit sliding and impingement abrasion and has a well deserved
reputation for its durability.
Temperature
V-THane will provide excellent service in cold
stores and Arctic conditions. Physical properties change little down to
-15°C, and while further reductions in temperature result in a gradual
stiffening, V-THane is still quite serviceable at -70°C. At higher temperatures
V-THane will provide good service up to 90°C and
is suitable for intermittent use at 120°C. Beyond these temperatures,
specially formulated materials are needed.
Radiation
V-THane polyurethanes offer superb resistance to
gamma ray radiation. Products exposed to 1 x 10 Roentgens continue to
give satisfactory service and are resistant to stress cracking.
Water
Resistance
Selected grades of V-THane polyurethane are suitable
for use in water at up to 50°C. Water absorption is very low and volume
swell is negligible. This means that precise components (eg polyurethane seals and polyurethane tubes) can be used safely
in water without fear of size changes affecting performance. High humidity
has little effect on V-THane and a secondary benefit
is that these elastomers do not support fungus growth and are generally
resistant to such attack. This makes V-THane mouldings
particularly suitable for tropical environments.
Ozone
and Oxygen
V-THane
polyurethane is highly resistant to ozone and oxygen attack. Tests conducted
at 2.1 Map oxygen pressure for 4 weeks show little change to physical
properties. The same result is obtained when tests are conducted at 3
ppm ozone for 500 hours. There is no measurable deterioration of the V-THane
and past experience indicates that materials which resist these concentrations
are virtually immune from atmospheric attack of ozone and oxygen.
Mechanical
Properties
At low hardnesses all elastomers, V-THane included,
merely bend under impact. As hardness rises elastomers and plastics demonstrate
a tendency to brittleness and crack under impact. V-THane
has significantly better impact resistance than any material of comparable
hardness. V-THane will resist cracking under repeated
flexing. Selection of the appropriate grade will allow extremely high
life spans, with tests proving that in excess of 1,000,000 cycles is common
place. V-THane will also show excellent resistance
to cut propagation and can be used in very thin sections because of its
exceptional strength and toughness.
Friction
V-THane resembles most other elastomers in that
friction decreases as hardness rises. The coefficient of friction against
non-Iubricated surfaces ranges from 0.2 (hard polymers) to 0.6 (soft polymers).
Machineability
It is possible to machine most grades of V-THane
polyurethane. The harder grades can be processed on most conventional
machine tools, while softer compounds need to be ground or cut with very
sharp tools.
Electrical
Properties
V-THane
generally has very good insulating properties and can be used for potting
and encapsulation. It is also an excellent material for mounting conductive
rails, particularly outside, where it not only provides good insulation
but also does not deteriorate.
Noise
The combination of compressive and flex characteristics make V-THane
ideal for breaking noise transmission paths. It makes superb heavy duty
machine mounts and can be utilised in fixing systems to provide a non-metallic
barrier.
Typical
V-THane Physical Properties
| Hardness
- Shore A |
35 |
45 |
60 |
70 |
80 |
90 |
95 |
| Tensile
Strength - MN/m2 |
16 |
20 |
24 |
28 |
34 |
34 |
30 |
| Angle
Tear Strength - KN/m |
20 |
26 |
40 |
58 |
70 |
105 |
90 |
| Elongation
at Break - % |
750 |
700 |
600 |
500 |
500 |
480 |
450 |
| Resilience
- % |
- |
65 |
55 |
50 |
45 |
35 |
35 |
| Compression
Set at 70°C - % |
20 |
10 |
40 |
45 |
45 |
40 |
40 |
| Taber
Abrasion (H22) - mg loss |
<15 |
<10 |
<10 |
<10 |
<10 |
<20 |
<30 |
Typical Supol Physical Properties
| Compounds |
Hardness
Range Shore A |
Maximum
Service Temperature °C |
Abrasion
Resistance |
Load
Bearing |
Resilience |
Tear
Resistance |
| Nitrile |
50-95 |
120 |
2 |
2 |
2 |
2 |
| EPDM |
25-95 |
150 |
2 |
2 |
2 |
3 |
| Hypalon
|
60-95 |
140 |
1 |
1 |
2 |
1 |
| Natural Rubber |
25-95 |
90 |
1 |
2 |
1 |
1 |
| Silicone |
35-85 |
235 |
4 |
4 |
1 |
4 |
Compatibility Chart for V-THane
& Supol Covered Rollers
|
V-THane®
Polyurethane |
Supol®
Natural Rubber |
Supol®
Nitrile |
Supol®
EPDM |
Supol®
Hypalon |
Supol®
Silicone |
| Abrasion
|
EXC
|
F |
F |
P |
G |
VP |
| Heat |
F |
F |
G |
G |
G |
VG |
| Aromatics |
G |
VP |
F |
F |
P |
P |
| Aliphatics |
EXC |
P |
EXC |
VP |
G |
F |
| Keytones & Esters |
F |
F |
VP |
EXC |
F |
P |
| Alcohols |
P |
G |
EXC |
VG |
VG |
P |
| Chlorinated
Solvents |
P |
VP |
F |
VP |
VP |
P |
| Oils |
VG |
P |
EXC |
P |
G |
F |
| Acid |
F |
F |
G |
F |
G |
F |
| Ozone |
EXC |
P |
P |
EXC |
EXC |
EXC |
| Water |
EXC |
EXC |
G |
EXC |
F |
G |
| Paraffinic |
EXC |
P |
EXC |
P |
F |
P |
At HPE,
we specialise in moulding high performance polyurethane components tailor
made to customer requirements providing a solution to a wide range of
application problems. We provide in-house development functions and can
often produce representative samples for customer trials. We are able
to identify a wide range of materials and can match samples where the
original specification or source is long forgotten.
Deal with the
experts for expert solutions.
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